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Pikachu
Pikachu is one of the most popular game characters of all time. He's also the smallest character in the game. As you should know by now, size never matters...especially when you're dealing with a creature with enough voltage to light a small town. 
Bio: Pikachu is the favorite Pokemon of Trainer Ash Ketchum. Pikachu has a carefree personality and makes friends easily, but if you provoke him, he has enough voltage to shock a Dragonite. Pikachu travels around the land with Ash, collecting Gym Badges, helping others and sending Team Rocket into the stratosphere every chance he gets.
Appearance: Pokemon (GB), Pokemon Stadium (N64), Pokemon Puzzle League (N64)
Ranking: Veteran (Super Smash Bros, Super Smash Bros Melee)
Super Smash Bros. / Super Smash Bros. Melee Moves:
Headbutt A Headbutt
Thunderbolt Forward + A Electric buzz saw Attack
Roundhouse Kick Forward, then A Kick to the body
Tail Whip Up + A Spin attack
Iron Tail Up, then A Overhead tail attack
Double Kick Down + A Kick to both sides
Circle Swipe Down, then A Swing tail around in a circle
Air Flip In mid jump, Up + A Tail Flip
Electric Spiral In mid jump, Forward + A Shock opponent while spinning
Grav Spin In mid jump, Down + A Downward Spin
Back Attack In mid jump, Back + A Kick backwards
Dash Attack Dash + A Running Head Butt
Thundershock B Send Electricity over platform
Thunder Down + B Lighting strikes Pikachu and shocks anyone 
standing nearby
Agility Up + B Charge, then jump really high
Shock Rocket Forward + B A very quick launching attack